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When both the 2.4ghz and 5G networks are initially set up, they will both have the same password. You can also follow this link to change your WIFI settings. Please keep in mind that any device using the 5G network will need to be 5G compatible (802.11 A/C).
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TWC-Social Media Customer Care
Moderator - TWC Community Forums
TWC can provide only information recommending that you consult the owner's manual of any device you are attempting to connect to the internet. The manufacturer of the device should advise as to which connection will provide the optimal performance. Ultimately, this is a case by case basis and there is not a universal response.